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Summary of VOC Emission Updates Updates to chemical mechanisms and Secondary Organic Aerosol Modules require additional emission species.

VOC Emission Species that are created with an emission processor such as SMOKE can be classified into 4 categories: For the Carbon Bond Mechanism, a list of VOC species names in CMAQ 5.0.2 and CMAQ 5.1 is provided as a reference: For CMAQ 5.1, SOAALK is a lumped SOA tracer species for all three mechanisms: CB05, SAPRC07, RACM2.

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There can be some confusion regarding the species name for Naphthalene.

We have elected the following convention for CB05/SAPRC07T/RACM2: NAPH refers to Naphthalene that is part of the VOC/TOG speciation NAPHTHALENE refers to the Naphthalene as estimated in the HAPS part of the NEI.

If you have an emission files without XYLMN, SOAALK, and NAPH, you can estimate these as follows: These estimates are approximate and are based on the 2011 NEIv1.

Use at your own discretion: 'SPC: MOLWT: EMIS_SUR: EMIS_FAC: ICBC_SUR: ICBC_FAC: DEPV_SUR: DEPV_FAC: SCAV_SUR: SCAV_FAC: G2AE_SUR: G2AQ_SUR: TRNS: DDEP: WDEP: CONC', 'ARO2MN:118.72: ARO2MN:1.0::::: O-XYLENE:1.0::: Yes:: Yes: Yes', 'NAPHTHAL:128.2: NAPH:1::::: O-XYLENE:1::: Yes::: Yes', 'SPC: MOLWT: EMIS_SUR: EMIS_FAC: ICBC_SUR: ICBC_FAC: DEPV_SUR: DEPV_FAC: SCAV_SUR: SCAV_FAC: G2AE_SUR: G2AQ_SUR: TRNS: DDEP: WDEP: CONC', 'ARO2MN:118.72: ARO2:1.0::::: O-XYLENE:1.0::: Yes:: Yes: Yes', 'NAPHTHAL:128.2::1::::: O-XYLENE:1::: Yes::: Yes', These approaches may have a minor effect on gas-phase chemistry and lead to slightly different aerosol estimates.

Carter Research Chemist Air Pollution Research Center and College of Engineering, Center for Environmental Research and Technology University of California, Riverside, CA, USA Mailing Address: CE-CERT, University of California, Riverside CA 92521 Phone: (909) 781-5797.

It has assignments for ~400 types of VOCs, and can be used to estimate reactivities for ~550 VOC categories.

Also, the April 3, 2000 data tabulation includes VOC classes that were not in the January 30 data set.

: Additional VOC classes requested by the CMA were added.

: The CARB requested the most recent MIR values for use in their regulatory programs.

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